In an article, published in an article, once mentioned the application of 7650-91-1, Name is Benzyldiphenylphosphine,molecular formula is C19H17P, is a conventional compound. this article was the specific content is as follows.name: Benzyldiphenylphosphine
The trihalophosphane complexes LnM-PHal3 (LnM = Cp(CO)2Mn, (CO)5Cr, (CO)5W; Hal = Cl, Br), upon treatment with Co2(CO)8, mainly yield clusters of the type Co3(CO)9(mu4-P)MLn with the (mu3-P)Co3(CO)9 unit acting as ligand.The analogous arsenic compound Co3(CO)9(mu4-As)Cr(CO)5 is obtained from the arsinidene complex <(CO)5Cr>2As-Cl with NaCo(CO)4.In addition to the syntheses and reactions of these clusters several reactions leading to clusters with mu4-P-, mu4-As, mu4-PR- and mu2-PR2 groups by reductive dehalogenation of coordinated halophosphanes are reported.The different types of compounds are documented by six X-ray-structure analyses.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate