13991-08-7, Name is 1,2-Bis(diphenylphosphino)benzene, molecular formula is C30H24P2, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 13991-08-7, SDS of cas: 13991-08-7
The bite angle of chelating diphosphines is often responsible for the activity and the selectivity of rhodium catalysts based on them. The EPR study of the composition and the structure of similar complexes with o-semiquinonic ligands is reported. The reaction of the diphosphines with dicarbonyl-o-semiquinonato rhodium complexes gives a variety of new products including o-semiquinonato complexes of monovalent rhodium and catecholates of divalent rhodium as well. Some of latter catecholates demonstrate the coordination sphere dynamics similar with Berry’s either turnstile mechanism. The composition, the structure and the properties of the formed compounds are defined by diphosphine bite angle.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.SDS of cas: 13991-08-7. In my other articles, you can also check out more blogs about 13991-08-7
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate