In an article, published in an article, once mentioned the application of 19845-69-3, Name is 1,6-Bis(diphenylphosphino)hexane,molecular formula is C30H32P2, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of 1,6-Bis(diphenylphosphino)hexane
A series of reactions of different silver thiolates, AgSR (R = Mes (mesityl), Nph (naphthyl), Cy (cyclohexyl)), with bidentate phosphanes was performed yielding a bunch of new compounds, which were characterized by single crystal X-ray diffraction. Depending on the nature of the thiolate and the phosphane the solid state structure of the products varies from discrete complexes or clusters to a 3-dimensional coordination network. The mesityl group favors the formation of trinuclear units which are then linked in one, e.g. [Ag3(SMes)3(dpph)2] (5), two, e. g. [Ag 3(SMes)3 (dpppt)2] (4), or three dimensions [Ag3(SMes)3(dppb)2] (3), via the phosphanes. With naphthyl and cyclohexyl groups mostly clusters are formed which are either isolated with some phosphanes in their ligand sphere, e.g. [Ag 12(SCy)12(dpppt)2] (13), or additionally linked by the phosphanes to form 1-dimensional chains, e.g. [Ag12(SCy) 12(dppo)] (17).
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate