Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 1486-28-8, Name is Methyldiphenylphosphine, molecular formula is C13H13P. In an article, author is Gao, Yao-Wei,once mentioned of 1486-28-8, COA of Formula: C13H13P.
Regio- and Enantioselective [3+2] Cycloaddition of alpha-Purine Substituted Acrylates with Allenes: An Approach to Chiral Carbocyclic Nucleosides
N-Heteroaromatic substituted acrylates are employed in the phosphine-catalyzed [3+2] annulation with allenes for the first time, affording regiospecific carbocyclic nucleoside analogues in an alpha-addition manner. Various chiral carbocyclic nucleoside analogues containing a quaternary stereocenter and a C=C double bond are generated in good yields (up to 90% yield) and excellent enantioselectivities (up to 97% ee). alpha-Purine-containing disubstituted acrylate and alpha-benzimidazole substituted acrylate are also suitable substrates for this reaction.
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Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate