Chemistry is an experimental science, Safety of 3,3′,3”-Phosphinetriyltripropanoic acid hydrochloride, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 51805-45-9, Name is 3,3′,3”-Phosphinetriyltripropanoic acid hydrochloride, molecular formula is C9H16ClO6P, belongs to chiral-phosphine-ligands compound. In a document, author is Zhang, Haiyan.
Cobalt-Catalyzed Diastereo- and Enantioselective Hydroalkenylation of Cyclopropenes with Alkenylboronic Acids
Catalytic diastereo- and enantioselective hydroalkenylation of 3,3-disubstituted cyclopropenes with readily accessible alkenylboronic acids, promoted by a chiral phosphine/Co complex, is presented. Such a process constitutes the unprecedented and direct introduction of a wide range of alkenyl groups onto the cyclopropane motif to afford multisubstituted cyclopropanes in up to 95 % yield with greater than 95:5 d.r. and 99:1 e.r. Functionalization of the products delivered enantioenriched cyclopropanes that are otherwise difficult to access.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 51805-45-9. Safety of 3,3′,3”-Phosphinetriyltripropanoic acid hydrochloride.
Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate