Reference of 7650-91-1, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 7650-91-1, Name is Benzyldiphenylphosphine, SMILES is P(C1=CC=CC=C1)(CC2=CC=CC=C2)C3=CC=CC=C3, belongs to chiral-phosphine-ligands compound. In a article, author is Cunillera, Anton, introduce new discover of the category.
Asymmetric Hydroformylation Using Rhodium
Asymmetric hydroformylation is a powerful catalytic reaction that produces chiral aldehydes from inexpensive feedstock (alkenes, syngas) in a single step. The elucidation of the different steps of the catalytic cycle and the characterization of the resting state, together with the discovery of several types of ligands, have made possible that nowadays a variety of chiral products incorporating a formyl unit can be enantioselectively prepared by Rh-catalyzed asymmetric hydroformylation, and that this process is now considered as a useful tool in organic synthesis.
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Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate