Reference of 7650-91-1, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, 7650-91-1, Name is Benzyldiphenylphosphine, SMILES is P(C1=CC=CC=C1)(CC2=CC=CC=C2)C3=CC=CC=C3, belongs to chiral-phosphine-ligands compound. In a article, author is Kang, Tian-Chen, introduce new discover of the category.
Enantioselective gamma-addition. reaction of rhodanines to allenoates catalyzed by chiral phosphine-carbamate
Phosphine-catalyzed enantioselective gamma-additions of rhodanines to allenoates have been developed for the first time. With the employment of chiral cyclohexane-based phosphines, a wide range of substituted rhodanine derivatives containing tertiary chiral centers were constructed in good yields and high enantioselectivities. (C) 2018 Elsevier Ltd. All rights reserved.
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Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate