A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1486-28-8, Name is Methyldiphenylphosphine, molecular formula is C13H13P. In an article, author is Nie, Shao-Zhen,once mentioned of 1486-28-8, Safety of Methyldiphenylphosphine.
Enantioselective Coupling of Dienes and Phosphine Oxides
We report a Pd-catalyzed intermolecular hydrophosphinylation of 1,3-dienes to afford chiral allylic phosphine oxides. Commodity dienes and air stable phosphine oxides couple to generate organophosphorus building blocks with high enantio-and regiocontrol. This method constitutes the first asymmetric hydrophosphinylation of dienes.
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Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate