6372-42-5, Name is Cyclohexyldiphenylphosphine, molecular formula is C18H21P, Name: Cyclohexyldiphenylphosphine, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, author is Sekine, Keisuke, once mentioned the new application about 6372-42-5.
Enantioselective Functionalization of Difluorocyclopropenes Catalyzed by Chiral Copper Complexes: Proposal for Chiral gem-Dimethyl and tert-Butyl Analogues
The highly enantioselective copper/chiral phosphine-catalyzed hydro-, bora-, and carbo-metalations of difluorocyclopropenes with PHMS [H-Si], H-BPin, (BPin)(2), and (CH3)(2)Zn [Zn-Me] are shown to regiodivergently afford highly enantioenriched and functionalized difluorocyclopropanes. These examples can be viewed as the first successful syntheses of chiral gem-dimethyl and tert-butyl analogues.
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Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate