Reference of 7650-91-1, Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice of redox mediator can avoid electrode passivation and overpotential. 7650-91-1, Name is Benzyldiphenylphosphine, SMILES is P(C1=CC=CC=C1)(CC2=CC=CC=C2)C3=CC=CC=C3, belongs to chiral-phosphine-ligands compound. In a article, author is Zagidullin, A. A., introduce new discover of the category.
Synthesis and asymmetric [4+2] cycloaddition reaction of 3,4,5-tripheny-1-1-((1R,2S,5R)-menthyl)oxymethyl-1,2-diphosphole
New chiral 3,4,5-triphenyl-1-((1R,25,5R)-menthyl)oxymethyl-1,2-diphosphole (1) was prepared by reaction of sodium 1,2-diphospholide with chloromethyl (1R,25,5R)-(-)-menthyl ether. The extent of asymmetric induction in the [4 + 2] cycloaddition reaction of chiral 1 with maleic anhydride was studied and the absolute configuration of the [4 + 2] cycloadducts determined by X-ray structure analysis. (C) 2020 Elsevier B.V. All rights reserved.
Reference of 7650-91-1, One of the oldest and most widely used commercial enzyme inhibitors is aspirin, which selectively inhibits one of the enzymes involved in the synthesis of molecules that trigger inflammation. you can also check out more blogs about 7650-91-1.
Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate