Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 6372-42-5, Name is Cyclohexyldiphenylphosphine, molecular formula is C18H21P, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, author is Yanagisawa, Akira, once mentioned the new application about 6372-42-5, Quality Control of Cyclohexyldiphenylphosphine.
Asymmetric Addition of Propargylic Silanes to Aldehydes Catalyzed by Chiral Phosphine-Silver Alkoxide Complex
A catalytic asymmetric addition of propargylic silanes to aldehydes was achieved using a DM-BINAP center dot AgBF4 complex as the chiral pre-catalyst and triethylamine as the base pre-catalyst in the presence of potassium fluoride and methanol. Optically active homoallenylic alcohols and homopropargylic alcohols were obtained in moderate to high combined yields via the in situ generated chiral organosilver species. Allenylated alcohols were formed predominantly with up to 95% ee.
We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, 6372-42-5. The above is the message from the blog manager. Quality Control of Cyclohexyldiphenylphosphine.
Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate