791-28-6, Name is Triphenylphosphine oxide, molecular formula is C18H15OP, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, author is Bayardon, Jerome, once mentioned the new application about 791-28-6, Quality Control of Triphenylphosphine oxide.
P-Chirogenic Triazole-Based Phosphine: Synthesis, Coordination Chemistry, and Asymmetric Catalysis
Herein we report the synthesis of a new P-chirogenic triazole-based phosphine according to the ephedrine methodology. Upon reaction with late transition-metal derivatives, Rh(I)and Pd-II, phosphine-triazole forms complexes with bidentate P,N coordination, as demonstrated by spectroscopic and X-ray crystallographic analyses. First experiments in asymmetric catalysis showed the catalytic potential of this new chiral P,N-type ligand.
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Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate