791-28-6, Name is Triphenylphosphine oxide, molecular formula is C18H15OP, Computed Properties of C18H15OP, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, author is Smaligo, Andrew J., once mentioned the new application about 791-28-6.
Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene-lmine [3+2] Annulation
We have prepared a previously unreported family of P-stereogenic [2.2.1] bicyclic chiral phosphines through straightforward syntheses starting from the natural product carvone. This design rationale prompted the development of an unforeseen C-dealkenylation reaction. We have applied these organocatalysts in the asymmetric syntheses of a bevy of pyrrolines, obtained in high yields and enantioselectivities, including a biologically active small molecule, efsevin.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 791-28-6 help many people in the next few years. Computed Properties of C18H15OP.
Reference:
Phosphine ligand,
,Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate