Related Products of 224311-51-7. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl
Rhodium(II)-Catalyzed C?H Bond Carboxylation of Heteroarenes with CO2
A method of RhII-catalyzed C?H carboxylation of 2-(imidazo[1,2-a]pyridin-2-yl)phenols via CO2 fixation under redox-neutral conditions was reported, providing an access to a range of coumarin derivatives. A suitable diphosphine ligand was crucial for this reaction. This reaction could be performed under relatively lower temperature or in a shorter time than the alternative base-promoted protocol.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate