Related Products of 224311-51-7, An article , which mentions 224311-51-7, molecular formula is C20H27P. The compound – 2-(Di-tert-Butylphosphino)biphenyl played an important role in people’s production and life.
Ruthenium catalyzed hydrogenation of methyl phenylacetate under low hydrogen pressure
PhCH2CO2Me has been efficiently hydrogenated to yield PhCH2CH2OH (1) and PhCH2CO2CH2CH2Ph (2) even under relatively low hydrogen pressure (< 10 atm) by using ruthenium-phosphine catalysis composed of Ru(acac)3, P(n-C8H17)3 in the presence of Zn. Effect of both P(n-C8H17)3 and Zn plays an essential role in order for this hydrogenation to proceed catalytically. Although the activity was not strongly influenced by the hydrogen pressure employed, the observed activity was strongly dependent upon the reaction temperature, substrate concentration, and solvent used. We assume that ruthenium hydride species plays an important role in this catalysis cycle. I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 224311-51-7, help many people in the next few years., Related Products of 224311-51-7
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate