In an article, published in an article, once mentioned the application of 224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl,molecular formula is C20H27P, is a conventional compound. this article was the specific content is as follows.category: chiral-phosphine-ligands
Kinetico-mechanistic studies on CX (X=H, F, Cl, Br, I) bond activation reactions on organoplatinum(II) complexes
The activation of CX bonds in homogeneous systems is a relevant topic in relation to important catalytic industrial processes involving organic substrates and producing high value-added compounds. However, despite the large amount of information that can be extracted from kinetico-mechanistic studies, as well as the improvement and availability of time-resolved and chemometric techniques, no generalisation of temperature and pressure mechanistic data about CX oxidative additions has been conducted so far. This review collects the information available from kinetico-mechanistic studies carried out on CX bond activation on PtII organometallic complexes in our groups, independently or in collaboration with others. Data concerning intermolecular CX bond activation at both mono and binuclear organoplatinum(II) compounds as well as intramolecular CX bond activation and associated reductive eliminations at organoplatinum(II) complexes are presented.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate