Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 13406-29-6, Name is Tris(4-(trifluoromethyl)phenyl)phosphine, Computed Properties of C21H12F9P.
Diiron propane-1,2-dithiolate complexes with monosubstituted tris(3-chlorophenyl)phosphine or tris(4-trifluoromethylphenyl)phosphine: synthesis, characterization, crystal structures, and electrochemistry
Two diiron propane-1,2-dithiolate complexes with monosubstituted tris(3-chlorophenyl)phosphine or tris(4-trifluoromethylphenyl)phosphine were synthesized and characterized. Treatment of the parent complex [Fe2(CO)6{mu-SCH2CH(CH3)S}] (1) with tris(3-chlorophenyl)phosphine or tris(4-trifluoromethylphenyl)phosphine and Me3NO¡¤2H2O as the decarbonylating agent afforded complexes [Fe2(CO)5P(3-C6H4Cl)3{mu-SCH2CH(CH3)S}] (2) and [Fe2(CO)5P(4-C6H4CF3)3{mu-SCH2CH(CH3)S}] (3) in 82% and 77% yields, respectively. Complexes 2 and 3 have been characterized by elemental analysis, IR, NMR spectroscopy, and X-ray diffraction analysis. Additionally, the electrochemical properties have been studied by cyclic voltammetry.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C21H12F9P. In my other articles, you can also check out more blogs about 13406-29-6
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate