The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, molecular formula is C34H28FeP2. In a Article£¬once mentioned of 12150-46-8, Quality Control of: 1,1-Bis(diphenylphosphino)ferrocene
One-pot synthesis and the X-ray structures of rhenium(I) diphosphine hydrides, fac-(CO)3(P-P)ReH [P-P = dppp, dppb, and dppfe]
Rhenium(I) tricarbonyl (diphosphine) hydrides have been synthesized in high yield from one-pot reaction of Re2(CO)10 with diphosphines in refluxed pentanol. The reactions of Re2(CO) 10 with chelated diphosphines, P-P, where P-P are 1,3-bis(diphenylphosphino)propane (dppp), 1,4-bis(diphenylphosphino)butane (dppb), and 1,1?-bis(diphenylphosphino)ferrocene (dppfe), in refluxed 1-pentanol or 1-hexanol afford the corresponding hydrides 1-3 fac-(CO) 3(P-P)ReH, (for 1, P-P is dppp, for 2, P-P is dppb, and for 3, P-P is dppfe) in high yield. The hydrides 1-3 have been characterized spectroscopically and by X-ray crystal structure determinations.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Quality Control of: 1,1-Bis(diphenylphosphino)ferrocene, you can also check out more blogs about12150-46-8
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate