In an article, published in an article, once mentioned the application of 166330-10-5, Name is (Oxybis(2,1-phenylene))bis(diphenylphosphine),molecular formula is C36H28OP2, is a conventional compound. this article was the specific content is as follows.Computed Properties of C36H28OP2
A four-coordinate Cu(I)?N-heterocyclic carbene complex: Synthesis, structure, properties, and application in amination for the synthesis of 1-(2-N-heteroaryl)-1H-pyrazoles
A new luminescent, cationic, heteroleptic, four-coordinate Cu(I)?N-heterocyclic carbene complex [Cu(Br-Pyim)(POP)](PF6) is successfully prepared and characterized, where Br-Pyim and POP are 1-(6-bromopyridin-2-yl)imidazole-3-benzyl-2-ylidene and bis[2-(diphenylphosphino)phenyl]ether, respectively. Its detailed structure is determined by single-crystal X-ray analysis. It exists as a crystalline powder at room temperature and exhibits bright yellow-green emission. The use of the Cu(I)?N-heterocyclic carbene complex as a catalyst for amination reactions is also investigated and is found to be very efficient for the amination of 2-N-heteroaryl chlorides with pyrazoles, giving the desired substituted 1-(2-N-heteroaryl)-1H-pyrazoles in good yields.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate