Application of 17261-28-8, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 17261-28-8, Name is 2-(Diphenylphosphino)benzoic acid, molecular formula is C19H15O2P. In a Article£¬once mentioned of 17261-28-8
A highly sensitive and selective fluorescent probe for nitroxyl based on a naphthalene derivative
In this work, we developed a novel fluorescent probe 1 for quantitative detection of nitroxyl (HNO). Probe 1 consisted of a naphthalene backbone and 2-(diphenylphosphino)benzoate which was used as a nitroxyl recognition unit. The probe exhibited an intense fluorescence turn-on response to nitroxyl via aza-ylide formation and its subsequent Staudinger ligation to release compound 2. The probe can be applied to the quantification of nitroxyl with a linear range from 5.0 ¡Á 10-8 to 9.0 ¡Á 10-6 mol L-1. The detection limit of probe 1 toward nitroxyl was estimated to be 43 nM. Furthermore, probe 1 displayed a much higher selectivity for nitroxyl than other biologically relevant species. Importantly, owing to the high cell permeability and low cytotoxicity of probe 1, it was successfully applied to cell imaging of nitroxyl in living cells. The probe is expected to be a useful chemical tool for investigating the detailed functions and mechanisms of HNO in living systems.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 17261-28-8 is helpful to your research., Application of 17261-28-8
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate