The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, molecular formula is C34H28FeP2. In a Article£¬once mentioned of 12150-46-8, category: chiral-phosphine-ligands
Regioselective c-f bond activation of hexafluoropropylene on palladium(0): Formation of a cationic H2-perfluoroallylpalladium complex
A chemoselective C(sp2) -F or C(sp3)-F bond activation of hexafluoropropylene (HFP) was achieved by adopting the proper combination of a Lewis acid co-additive with a ligand which coordinates Pd0. The treatment of [(h2- HFP)Pd(PCy3)2] with B(C6F5)3 allowed a chemoselective C- (sp3)-F bond cleavage of HFP to give a unique cationic perfluoroallypalladium complex. In this complex, the coordination mode of the perfluoroallyl ligand was considered to be of the unique h2-fashion.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.category: chiral-phosphine-ligands, you can also check out more blogs about12150-46-8
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate