The Absolute Best Science Experiment for 12150-46-8

Electric Literature of 12150-46-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene

Reactivity of a (Fe-NO)-(Fe-NO3) system in the presence of a ferrocene-ferricinium group tethered nearby via a ferrocenyl phosphine linkage (FcP2): crystal structures of <2(mu-FcP2)> and

The nitrosyl dimer <2> (1) reacts with 1,1′-bis(diphenylphosphino)ferrocene (FcP2) to yield 2(mu-FcP2) (2), the structure of which has been determined.The FcP moiety bridges two Fe(NO)2(Cl) groups symmetrically.Oxygenation of 1 in the presence of FcP2 yields (5): Complex 5 catalyses the autoxidation of cyclohexene.It transfers the oxygen atoms of its nitrato groups to phosphines.When allowed to react with an excess of FcP2, 2 gives (4); the subsequent formation of (3) is attributed to th e reaction of 4 with chlorine liberated in situ.The structure of 4 was also determined.Keywords: Iron; Nitrosyl; Ferrocene ligand; Nitrato complex; X-ray diffraction; Oxidation

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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate