1038-95-5, Name is Tri-p-tolylphosphine, molecular formula is C21H21P, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 1038-95-5, Product Details of 1038-95-5
[Pd(acac)(L)2][BF4] (L?=?morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity
Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)2][BF4] with L (L?=?morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)2][BF4] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}2][BF4] establishes the presence of hydrogen bonding between the morpholine ligand and [BF4]? anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}2][BF4] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 1038-95-5. In my other articles, you can also check out more blogs about 1038-95-5
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate