In an article, published in an article, once mentioned the application of 1608-26-0, Name is Tris(dimethylamino)phosphine
,molecular formula is P[N(CH3)2]3, is a conventional compound. this article was the specific content is as follows.Computed Properties of P[N(CH3)2]3
Enthalpy of solution and hydrophobic effects in the water-hexamethylphosphorotriamide-tetrabutylammonium bromide system at 298.15 K
The heat effects of solution of tetrabutylammonium bromide (TBA) in water-hexamethylphosphorotriamide (HMPT) mixed solvents were measured over the whole range of solvent compositions on a variable-temperature isothermic-shell calorimeter. The standard enthalpies of solution of TBA and its transfer from HMPT to HMPT-water mixtures were calculated. The McMillan-Mayer model as used to calculate the electrolyte-HMPT pair interaction coefficient. The state of the Bu4N+ ion in water and water-HMPT mixtures was studied in terms of the clathrate model. The results were compared with literature data on mixtures of water with dimethylformamide, dimethylsulfoxide, and dimethylamine.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate