In an article, published in an article, once mentioned the application of 1608-26-0, Name is Tris(dimethylamino)phosphine
,molecular formula is P[N(CH3)2]3, is a conventional compound. this article was the specific content is as follows.Safety of Tris(dimethylamino)phosphine
ZUR REAKTION VON P(III)AMIDEN MIT ORTHOAMEISENSAEUREESTERCHLORIDEN
Both ester diamide, 2a, as well as diester amide, 2b, derivatives of phosphorous acid react with trichlorobenzodioxole, 1, to form the expected ester amide, 3, in small yields only.The main product is the dioxaphosphole, 4.Likewise, trisdimethylaminophosphine reacts with 1 with formation of the dioxaphosphole, 7.This unexpected reaction may be rationalized by assuming competition between N- and P-“diaryloxymethylenation” of the P(III)amide.A similar competition has been observed in the reaction of orthoformate with bis(dimethylamino)chlorophosphine.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate