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Chapter 8: C-C Bond Formation in the Sustainable Synthesis of Pharmaceuticals
In this chapter, applications of transition metal-catalysed C-C coupling reactions with significance for the manufacture of active pharmaceutical ingredients (APIs) and other drug components in the pharmaceutical industry are presented. Currently, a vast number of biologically active compounds can be prepared under mild conditions from easily available substrates through cross-coupling reactions, highlighting their versatility, functional group tolerance and effectiveness. The C-C coupling reactions herein selected are those most commonly used as key steps in methodology design for the sustainable production of pharmaceuticals.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate