In an article, published in an article, once mentioned the application of 224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl,molecular formula is C20H27P, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of 2-(Di-tert-Butylphosphino)biphenyl
Catalytic hydrogenation of aromatic and aliphatic nitriles in organic/aqueous biphasic system
Hydrogenation of aromatic and aliphatic nitriles catalyzed by RuCl 3-TPPTS complex in organic/aqueous biphasic system was studied. Benzonitrile and its derivates with different substituted groups were almost completely converted to corresponding alcohols with the selectivities of 99.8%. The conversions of benzeneacetonitrile and 3-phenyl propionitrile decreased greatly, but the selectivities to the corresponding alcohol could still keep 97%. The hydrogenation of aliphatic nitriles did not occur in the same conditions.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate