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Synthesis and thermolysis of novel spiroselenuranes bearing two oxaselenetane rings: Double oxirane formation reactions from 1,5-dioxa-4lambda4-selenaspiro[3.3]heptanes

The first stable spiroselenuranes bearing two oxaselenetane rings have been synthesized, characterized by X-ray crystallographic analysis, and shown to be thermally reactive giving two molar equivalents of the corresponding oxirane with elimination of elemental selenium, in sharp contrast to the behavior of the phosphorus and silicon analogues.

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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate