Can You Really Do Chemisty Experiments About 4020-99-9

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In an article, published in an article, once mentioned the application of 4020-99-9, Name is Methoxydiphenylphosphine,molecular formula is C13H13OP, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of Methoxydiphenylphosphine

ALKYL- UND ARYLKOMPLEXE DES IRIDIUMS UND RHODIUMS. XV. PHOSPHONIT- UND PHOSPHINITINDUZIERTE CO-INSERTIONS- UND C-H-ADDITIONSREAKTIONEN ortho-METHYLSUBSTITUIERTER IRIDIUMARYLE. REVERSIBLE CH3-METALLIERUNG IM PHOSPHINITKOMPLEX

The synthesis of a series of cyclometallated hydrido-iridium(III) compounds fac- (Ar = C6H4: R = R’ = OMe.Ar = C6H2Me2-4,6:R = OMe, OEt, Ph; R’ = OMe, OEt) from iridium(I) aryls Ir(CO)(PPh3)2 and phosphonites or phosphinites is reported.As a result of a reversible methyl-to-metal hydrogen transfer the tris(phosphinite) complex exists in solution in an equilibrium with Ir(CO)(Ph2POMe)2 and Ph2POMe.The demetallated iridium(I) compound predominates in this equilibrium which may be shifted in favour of the metallacyclic component by addition of excess phosphinite.

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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate