Extracurricular laboratory:new discovery of 2-(Diphenylphosphino)benzoic acid

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17261-28-8, An article , which mentions 17261-28-8, molecular formula is C19H15O2P. The compound – 2-(Diphenylphosphino)benzoic acid played an important role in people’s production and life.

Directed branched-regioselective hydroformylation of 2-substituted allylic o-DPPB esters

Branched-regioselective hydroformylation of allylic o-DPPB esters has been accomplished with mono- and disubstituted alkene functions in good to excellent yields and selectivities. Optimized reaction conditions allowed the reaction of even trisubstitued alkenic functions. These reactions occur as a result of a significant rate-accelerating effect exerted by the catalyst-directing o-DPPB group, as exemplified by highly position-, regio-, and diastereoselective hydroformylation of the geranyl and neryl o-DPPB esters. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate