Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1038-95-5, Name is Tri-p-tolylphosphine, 1038-95-5.
Synthesis and characterization of new nitrate-bridged polymeric complexes of mercury(II) with phosphorus ylides
Reaction of phosphorus ylides of the type X-C6H4-COCH{double bond, long}PAr3 (X = Cl and NO2; Ar = phenyl and p-tolyl) with Hg(NO3)2 ¡¤ H2O in equimolar ratios using methanol as solvent are reported. X-ray crystal structure analysis of [Hg(ClC6H4C(O)CHPPh3)(NO3) (mu-NO3)]n ¡¤ (DMSO)n shows that the 1:1 complex adopts the noncentrosymmetric polymeric structure in the solid state with NO-3 anion bridges. Variation of temperature or concentration in a 31P NMR study indicates that the disappearance of satellites, due to coupling to 199Hg, occurs at increasing temperature or decreasing concentration.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.1038-95-5. In my other articles, you can also check out more blogs about 1038-95-5
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate