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1038-95-5, In an article, published in an article,authors is Bandyopadhyay, Pinaki, once mentioned the application of 1038-95-5, Name is Tri-p-tolylphosphine,molecular formula is C21H21P, is a conventional compound. this article was the specific content is as follows.
Bis(arylazo-oximato)palladium(II); Synthesis, Palladium-Nitrogen Bond Lability, and Redox Activity
The synthesis and characterisation of the title complex, , and related mixed-ligand complexes including (A = ortho-metallated azobenzene) are described.The mass spectrum of reveals peaks corresponding to loss of oximato-O and NO from the parent ion.Gaseous HCl cleaves the Pd-N(oxime) bond selectively.Triphenylphosphine cleaves one or both Pd-N(azo) linkages giving and unstable which is also produced by oxidative addition of HL to .In the unidentate and bidentate L groups scramble rapidly at 308 K but slowly at 233 K (1H n.m.r.).Bidentate phosphine and phosphinoarsine cleave the two Pd-N(azo) bonds simultaneously.Unidentate amines, when present in very large excess, produce unstable in which one L is unidentate.Addition of X2 (X= Cl or Br) yields the unstable palladium(IV) complex which is readily reduced to halogeno-bridged palladium(II) species.A cyclic-voltammetric study of the one-electron quasi-reversible reduction of , , etc. at a platinum electrode is briefly reported.
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Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate