Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 7650-91-1, Name is Benzyldiphenylphosphine, 7650-91-1.
Synthesis and 13C NMR study of the triangulo-clusters [Pt3(mu-CO)3 – (n)(mu-SO2)(n)(PR3)3] (n = 0-3)
[Pt3(mu-CO)3(PPh3)3] was prepared in high yield by the reaction of [Pt3(mu-CO)3(PPh3)4] with H2O2. The carbonyl ligands in [Pt3(mu-CO)3(PR3)3] (PR3 = PPh3, PPh2Bz, PCy3, P(i)Pr3) may be completely replaced by sulfur dioxide to give [Pt3(mu-SO2)3(PR3)3] or partially by one SO2 to give [Pt3(mu-CO)2(mu-SO2)(PR3)3] (PR3 = PCy3 and P(i)Pr3). On the other hand, the addition of one molar equivalent of carbon monoxide to [Pt3(mu-SO2)3(PR3)3] (PR3 = PCy3; P(i)Pr3) gave the complexes [Pt3(mu-CO)(mu-SO2)2(PR3)3]. Complete simulation of the 13C NMR spectra could be achieved with the help of 195Pt NMR data. (C) 2000 Elsevier Science S.A.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.7650-91-1. In my other articles, you can also check out more blogs about 7650-91-1
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate