657408-07-6. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 657408-07-6, Name is Dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine
Straightforward approach to norbornene core based chiral ligands by tandem cross dehydrogenative coupling reactions
The first synthesis of rigid pentacyclic NORPHOS derivatives by a tandem cross-coupling/cross-dehydrogenative-coupling according to the Catellani reaction protocol is reported. Mediated by palladium complexes of C,P-chelating monophosphine ligands, the readily available enantiopure NORPHOS oxide underwent a stereo- and regio-selective cyclocondensation reaction with arylhalides involving the activation of two unreactive C?H bonds.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. 657408-07-6, In my other articles, you can also check out more blogs about 657408-07-6
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate