166330-10-5. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 166330-10-5, Name is (Oxybis(2,1-phenylene))bis(diphenylphosphine), molecular formula is C36H28OP2.
Highly effective luminescence stemmed from thermally activated delayed fluorescence (TADF) and phosphorescence for the new four-coordinate copper(I) complexes containing N-heterocyclic carbene (NHC) ligands
The two four-coordinate N-heterocyclic carbene (NHC) copper(I) complexes, [Cu(Ph-BenIm-methylPy)(POP)]PF6 (1), and [Cu(Ph-Im-methylPy)(POP)]PF6 (2) Ph-BenIm-methylPy = 3-benzyl-1-(6-methyl-pyridin-2-yl)-1H-benzimidazolylidene, Ph-Im-methylPy = 3-benzyl-1-(6-methyl-pyridin-2-yl)-1H-imidazolylidene, POP = bis[2-diphenylphosphino]-phenyl)ether) have been synthesized and characterized. Those complexes exhibit blue to green emission with very high quantum yields and long excited-state lifetimes. The experimental results reveal that the origin of emissive state at room temperature occurs from the combination of TADF and phosphorescence in which phosphorescence predominates TADF, and the corresponding emissive mechanisms were discussed. To the best of our knowledge, the combined emissions with high quantum yield close to ca. 100% have not been previously reported in this library of the four-coordinate NHC-Cu(I) complexes.
166330-10-5, The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 166330-10-5 is helpful to your research.
Reference£º
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate