An article , which mentions 224311-51-7, molecular formula is C20H27P.224311-51-7, The compound – 2-(Di-tert-Butylphosphino)biphenyl played an important role in people’s production and life.
Dramatic mechanistic switch in Sn/AuI group exchanges: Transmetalation vs. oxidative addition
The mechanism of Ph/X exchange in reactions involving SnPhnBu3 and [AuXL] complexes switches dramatically from the usual concerted mechanism involving Ar/X mixed bridges when X = Cl, to an unexpected oxidative addition/reductive elimination pathway via an AuIII intermediate when X = vinyl.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate