5931-53-3,5931-53-3, Diphenyl(o-tolyl)phosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: Equimolar amounts of KSeCN (5.8 mg, 0.04 mmol) andeither diphenyl(ortho-tolyl)phosphane (11.1 mg, 0.04 mmol)or dicyclohexyl(ortho-tolyl)phosphane (11.5 mg, 0.04 mmol)were dissolved in the minimum amount of MeOH (10 ml). TheKSeCN solution was added dropwise (over a period of 5 min)to the phosphane solution with stirring at room temperature.Slow evaporation of the solvent afforded the title compoundsas colourless crystals suitable for single-crystal X-ray studies.Analytical data for I, 31P {H} NMR (CDCl3, 161.99 MHz):32.03 [t, 1J(31P-77Se) = 714 Hz]
The synthetic route of 5931-53-3 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Davis, Wade L.; Muller, Alfred; Acta Crystallographica Section C: Structural Chemistry; vol. 75; (2019); p. 1310 – 1318;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate