932710-63-9, 4-(Di-tert-butylphosphino)-N,N-dimethylaniline is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
932710-63-9, The procedure used to prepare 1a was modified to replace the HgCl2 addition with 0.032 g (0.1 mmol) Hg(SCN)2. After 3 days,white crystals suitable for X-ray analysis were obtained. Yield:0.046 g, 68% based on Hg(SePh)2.Properties: white crystalline substance. Melting point: 195-197 C. Anal. Calc. for C46H66Hg2N4P2S2Se2 (1360.18): Hg, 29.49;Se, 11.61; C, 40.62; H, 4.89; N, 4.12. Found: Hg, 29,40; Se, 11.58;C, 40.81; H, 4.83; N, 4.11%. IR (KBr): 3064 [vs(CAH)]; 2951[vas(CH3)]; 2874 [vs(CH3)]; 2101 [v(SCN)]; 1595, 1472, 1435[vs(CC)]; 1370 [v(CAN)]; 1066, 1021 [dip(CCAH)]; 744, 692[dop(CCAH)]; 507 [v(PAC)]; 465 cm1 [dop(CCAC)] (dip anddop = in-plane and out-of-plane bending motions, respectively).
932710-63-9 4-(Di-tert-butylphosphino)-N,N-dimethylaniline 11714598, achiral-phosphine-ligands compound, is more and more widely used in various fields.
Reference£º
Article; Stieler, Rafael; Faoro, Eliandro; Cechin, Camila Nunes; Floriano, Luana; Lang, Ernesto Schulz; Journal of Molecular Structure; vol. 1079; (2014); p. 9 – 14;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate