18437-78-0, Tris(4-fluorophenyl)phosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: The synthesis of the cyclopalladated compounds have been carried out using the procedure described by Onue etal. [16] with minor modifications. In a general procedure, to a stirred suspension of [PdCl(C2,N-aphox)]2 (100mg, 0.18mmol) in 10mL of acetone, 0.38mmol of the suitable phosphine ligand (mass of reactants: L1=99.8, L2=120.3, L3=106.7, L4=105.1, L5=134.0, L6=115.8mg) dissolved in 5mL of acetone was added dropwise, affording a yellow solution. The mixture was stirred for 1hat room temperature and slow evaporation of the final solutions at room temperature afforded crystals in good yields. The crystals were collected, washed with pentane and dried under vacuum. Suitable single crystals for X-ray diffraction determination of 1?5 have been obtained by slow evaporation of a solution containing 2?5mg of the complex in 5mL of acetone. Yellow crystals were obtained after 1 week., 18437-78-0
The synthetic route of 18437-78-0 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Bozza, Gabriela F.; de Farias, Renan L.; de Souza, Ronan F.F.; Rocha, Fillipe V.; Barra, Carolina V.; Deflon, Victor M.; de Almeida, Eduardo T.; Mauro, Antonio E.; Netto, Adelino V.G.; Journal of Molecular Structure; vol. 1175; (2019); p. 195 – 207;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate