6224-63-1, Tri-m-tolylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: To a magnetically stirred solution of a N-formyl/thiourea (2 mmol) and a triarylphosphine (2 mmol) in dry EtOAc (10 mL) was added dropwise, a dialkyl acetylenedicarboxylate (2 mmol) in dry EtOAc (5mL) at room temperature over 10 min. The progress of the reaction was monitored by thin-layer chromatography with n-hexane-ethyl acetate(1:1 v/v) mixture as eluent. After completion of the reaction the solvent was removed under reduced pressure and the solid residue was washed with cold diethyl ether (2 ¡Á 5 mL) and the product was obtained., 6224-63-1
6224-63-1 Tri-m-tolylphosphine 80362, achiral-phosphine-ligands compound, is more and more widely used in various fields.
Reference£º
Article; Shams, Nasim; Mosslemin, Mohammad Hossein; Yazdani, Afshin; Anaraki-Ardakani, Hossein; Ghane, Javad; Journal of Chemical Research; vol. 40; 6; (2016); p. 351 – 353;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate