7650-91-1, Benzyldiphenylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
7650-91-1, In the Ar atmosphere,1.0 mmol of the compound of the structure of the formula (3) (wherein R1 and R2 are each independently hydrogen; synthesized by the method of Organometallics 2008, 27, 88-99) were dissolved in 50 mL of anhydrous THF, and then 1.0 mmol of the azide compound of the structure represented by the formula (4) (R3 is a phenyl group, commercially available from ALDRICH) was added,The reaction was stirred at 15 [deg.] C for 12 hours.The resulting reaction solution was concentrated to about 10 ml,2 mL of n-hexane was added (keeping the solution clear).The mixture was stored at -30 overnight,Precipitation ligand.The resulting solid was filtered,Washed with a small amount of n-hexane,Vacuum drying,To obtain ligand L1.Ligand L1 was analyzed,The results are as follows:
The synthetic route of 7650-91-1 has been constantly updated, and we look forward to future research findings.
Reference£º
Patent; Sinopec China Petroleum & Chemical Corporation; Sinopec Beijing Research Institute of Chemical Industry; Sun, Wei; Xin, Yishuang; Shao, Mingbo; Li, Chuanqing; Wang, Xue; Zhao, Jiangwei; (18 pag.)CN105985382; (2016); A;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate