With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.19845-69-3,1,6-Bis(diphenylphosphino)hexane,as a common compound, the synthetic route is as follows.
General procedure: [Cu(CH3CN)4][ClO4] (65.2mg, 0.200mmol) was added to a degassed DCM solution (about 10mL) of BrbpyBr (62.4mg, 0.200mmol) and dppm (78.4mg, 98%, 0.200mmol). The color of the solution gradually changed to pale yellow. The solution was then stirred for 5h at room temperature. After filtration, layering n-hexane onto the DCM solution gave the product as pale yellow crystals., 19845-69-3
19845-69-3 1,6-Bis(diphenylphosphino)hexane 2754312, achiral-phosphine-ligands compound, is more and more widely used in various fields.
Reference£º
Article; Li, Xiu-Ling; Xin, Xue-Lian; Ai, Yu-Bo; Tan, Ming; Lu, Han; Du, Bai-Xiang; Inorganica Chimica Acta; vol. 401; (2013); p. 58 – 63;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate