1608-26-0, N,N,N’,N’,N”,N”-Hexamethylphosphinetriamine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: To a stirred suspension of Ph3P (12.5 mmol, 3280 mg) in dry MeCN (25 mL) solid N-aryl-2-nitrosoaniline 5 (5 mmol) was added portionwise during 30 min under external cooling with coldwater, and the mixture was stirred at r.t. overnight. The precipitated solid was filtered off, the filtrate was concentrated under vacuum and the residue was chromatographed using hexane-EtOAc gradient elution (9:1 to 2:1). An analytically pure sample of the product was obtained by recrystallization from EtOAc-hexane.
1608-26-0, 1608-26-0 N,N,N’,N’,N”,N”-Hexamethylphosphinetriamine 15355, achiral-phosphine-ligands compound, is more and more widely used in various fields.
Reference£º
Article; ?ukasik, Emilia; Wrobel, Zbigniew; Synthesis; vol. 48; 8; (2016); p. 1159 – 1166;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate