6224-63-1, Tri-m-tolylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
2mmol NaOH (0.080g) is dissolved in 10ml of methanol and 2mmol of carbon disulfide (CS2) (0.150g, 120mul, density=1.266g/ml) is then added. The clear solution is then added to a 10ml acetonitrile solution which contains 0.5mmol AgNO3 (0.085g) and 1mmol tri-aryl-phosphines (tpp: 0.262g (1), 0.304g, tptp and tmtp: 0.304g (2 and 3)). The mixture was stirred for 3h at 0¡ãC and the resulting yellow solution was filtered off. Colorless crystals of 1?3 suitable for X-ray analysis were grown from slow evaporation of the solution after 2days., 6224-63-1
As the paragraph descriping shows that 6224-63-1 is playing an increasingly important role.
Reference£º
Article; Banti, Christina N.; Kourkoumelis, Nikolaos; Tsiafoulis, Constantinos G.; Skoulika, Stavroula; Hadjikakou, Sotiris K.; Polyhedron; vol. 121; (2017); p. 115 – 122;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate