With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.24171-89-9,Tri(thiophen-2-yl)phosphine,as a common compound, the synthetic route is as follows.
A CH2Cl2 solution (30 mL) of [Fe3(CO)12] (200 mg, 0.40 mmol) and PTh3 (111 mg, 0.40 mmol) was heated to reflux for 12 h. The solvent was removed under reduced pressure and the residue chromatographed by TLC on silica gel. Elution with hexane/CH2Cl2 (v/v 9:1) developed two bands [Fe2(CO)6(mu-eta1,eta2-Th)(mu-PTh2)] (3) (160 mg, 72%) as light orange crystals and [Fe2(CO)5(mu-eta1,eta2-Th)(mu-PTh2)(PTh3)] (4) (6 mg, 2%) as deep orange crystals., 24171-89-9
The synthetic route of 24171-89-9 has been constantly updated, and we look forward to future research findings.
Reference£º
Conference Paper; Rahaman, Ahibur; Alam, Fakir Rafiqul; Ghosh, Shishir; Haukka, Matti; Kabir, Shariff E.; Nordlander, Ebbe; Hogarth, Graeme; Journal of Organometallic Chemistry; vol. 730; (2013); p. 123 – 131;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate