With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.12150-46-8,1,1-Bis(diphenylphosphino)ferrocene,as a common compound, the synthetic route is as follows.
The solutions of (0.0256 g, 0.1 mmol) of H2dzin 10 cm3 of methanol, (0.1 mmol, 0.0233 g) ofMnCl2.6H2O in 10 cm3 of methanol) and (0.0554 g,0.1mmol of 1,1′-bis(diphenyl phosphine) ferrocene(dppf) were mixed and refluxed at 55 oC for 2 h to give brown colored precipitate and the solutionswas filtered and finally it was dried in an open air.Yield=81percent, d.p= 238¡ãC. Anal. Calc. percent for C47 H41 ClN4 P2Mn S Fe:C, 62.58; H, 4.58; N, 6.21, S, 3.55, Mn,6.09, Cl, 3,93 .Found percent: C, 62.87, H, 4.82; N, 6.53, S;3.88, Mn; 6.27, Cl.4.11.
12150-46-8, The synthetic route of 12150-46-8 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Mohamad, Hikmat Ali; Oriental Journal of Chemistry; vol. 34; 4; (2018); p. 1919 – 1925;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate