24171-89-9, Tri(thiophen-2-yl)phosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: To a solution of [Fe2(CO)6(mu-SCH2CH2S)] (0.037 g, 0.1 mmol) and tricyclohexylphosphine (0.028 g, 0.1 mmol) in CH2Cl2 (5 mL) was added a solution of Me3NO¡¤2H2O (0.011 g, 0.1 mmol) in MeCN (5 mL). The mixture was stirred at room temperature for 1 h, and then, the solvent was reduced on a rotary evaporator. The residue was subjected to TLC using CH2Cl2/petroleum ether = 1:3 (v/v) as eluent. From the main red band, 0.042 g (68%) of complex 2 was obtained as a red solid., 24171-89-9
The synthetic route of 24171-89-9 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Yan, Lin; Li, Ao; Xiao, Qi-Min; Liu, Xu-Feng; Li, Yu-Long; Jiang, Zhong-Qing; Wu, Hong-Ke; Transition Metal Chemistry; vol. 44; 5; (2019); p. 483 – 489;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate