6372-42-5, Cyclohexyldiphenylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated,6372-42-5
General procedure: A mixture of AgBr (0.018g, 0.1mmol), diphenyl(p-tolyl) phosphine (P5) 0.028g (0.1mmol) and thiosemicarbazide (L1) 0.018g (0.2mmol) in 20ml of acetone/ methanol (1:1) was refluxed with continuous mechanical stirring overnight at 70C. The light yellow transparent solution obtained was filtered to avoid any impurity and slow addition of water resulted precipitation of final product. The product was collected by filtration, washed with water and dried. Again in situ transformation of L1 to L2 had taken place. Yield 0.078g, 89%. Anal. Calc. for C42H43AgBrN3P2S: C, 57.8; H, 4.9; N, 4.8. Found: C, 57.8; H, 4.9; N, 4.8%. IR cm-1: 3531 (w), 3479 (m), 3413 (m), 3119 (s), 2926 (s), 2842 (s), 1633 (s), 1608 (s), 1546 (m), 1456 (s), 1384 (s), 1148 (m), 1058 (s), 989 (ms), 819 (m), 767 (m), 666 (s), 521 (m).
The synthetic route of 6372-42-5 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Altaf, Muhammad; Stoeckli-Evans, Helen; Cuin, Alexandre; Sato, Daisy Nakamura; Pavan, Fernando Rogerio; Leite, Clarice Queico Fujimura; Ahmad, Saeed; Bouakka, Mohammed; Mimouni, Mostafa; Khardli, Fatima Zahra; Hadda, Taibi Ben; Polyhedron; vol. 62; (2013); p. 138 – 147;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate