18437-78-0, Tris(4-fluorophenyl)phosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: To a solution of complex 1 (0.245 g, 0.5 mmol) in MeCN (15 mL) was added the decarbonylation reagent Me3NO¡¤2H2O (0.056 g, 0.5 mmol). The mixture was stirred at room temperature for 10 min and then PPh3 (0.131 g, 0.5 mmol) was added. The resulting mixture was stirred for additional 2 h to give a dark red solution. Solvents were removed under vacuum and the residue was subjected to TLC using CH2Cl2/petroleum ether (v/v = 1:20) as the eluent. From the main red band, complex 2 (0.152 g, 42percent) was obtained as a dark red solid.
18437-78-0, The synthetic route of 18437-78-0 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Li, Yu-Long; He, Jiao; Wei, Juan; Wei, Jian; Mu, Chao; Wu, Yu; Xie, Bin; Zou, Li-Ke; Wang, Zheng; Wu, Mei-Li; Li, Han-Min; Gao, Fan; Zhao, Pei-Hua; Polyhedron; vol. 137; (2017); p. 325 – 331;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate