6372-42-5, Cyclohexyldiphenylphosphine is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated,6372-42-5
A large amount of phosphorescent cuprous complex CuI (2-PBO) (PPh 2 Cy) crystal the preparation of the sample: weighing 0.5mmol CuI of dissolved in 12 ml in acetonitrile, weighing 0.5 diphenyl cyclohexyl phosphine biligand dissolved in 10 ml of methylene chloride, the two kind of solution mixing, and stirring to make fully undergo coordination reaction to obtain the colorless solution A; then weighing 0.5mmol the 2-PBO biligand dissolved in 10 ml of acetonitrile, then to add the solution of the above-mentioned solution in A, and stirring to make fully undergo coordination reaction, finally the resulting orange-yellow reaction the fluid turns on lathe steams remove all solvent, vacuum drying, the obtained product is orange yellow crystal, yield 94% (to cu meter).
6372-42-5 Cyclohexyldiphenylphosphine 80756, achiral-phosphine-ligands compound, is more and more widely used in various fields.
Reference£º
Patent; China University of Metrology; Chai, Wenxiang; Zhu, Qiumeng; Song, Li; Chen, Gang; Guo, Bing; Chen, Zhi; Qin, Laishun; (9 pag.)CN105777785; (2016); A;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate